Dating back to an idea proposed in 2004, the past several years have witnessed the emergence of a new paradigm in alloy design, in which three or more elements are mixed in roughly equal proportions. Named multiprincipal element alloys (MPEAs) – but often known as a subset of these alloys called high-entropy alloys – these materials blur the distinction between majority and minority populations of elements. This more perfect union of atomic partners can produce collective materials that exhibit exciting properties that allow them to perform better than their traditional counterparts.

“Some of these materials exhibit exceptional combinations of strength, ductility and damage tolerance,” writes a team of researchers at the University of California (UC), Santa Barbara – including materials professors Dan Gianola, Tresa Pollock and Irene Beyerlein, and postdoctoral researcher Fulin Wang – and their co-authors in a paper in Science. “Refractory alloys [made from a group of nine metal elements on the periodic table that are highly resistant to heat and wear] are attractive candidates for use at extremely high temperatures associated with many technology applications.”

MPEAs motivated the development of refractory MPEAs, first made in 2010. But using multiple elements almost infinitely increases the number of possible alloy ‘recipes’. The sheer number of combinations that can be achieved sets the stage for the use of advanced computational screening and machine learning to identify the materials subsets with the most interesting and desirable properties.

The crystalline structures of metals are made up of stacked planes of atoms organized into a highly regular grid. When a metal deforms, atoms move or slide over each other on the grid. The line separating the regions where atoms have moved and where they have not is called a dislocation. The properties of dislocations, including how easily and where they can move, therefore become very important to the deformation behaviors of metals.

While traditional trial-and-error approaches to developing alloys have proved inefficient, from about 2017 more research efforts have been devoted to developing theories to try to identify the underlying reason that a particular alloy had desirable properties.

In this study, the researchers used electron microscopy to investigate the configurations of dislocations and unveil the mechanistic origins that give rise to desirable properties in a model alloy. Combined with atomistic simulations from the group of Irene Beyerlein, they showed that the random field of different elements unlocks multiple pathways for dislocation movements. Such multiple pathways are not available in conventional alloys.

“For conventional dislocations, the force to break atomic bonds at a dislocation is single valued because all the atoms are alike,” Beyerlein explained. “For the MPE dislocation, this force cannot be deterministic. The structure of an MPE dislocation becomes redefined as it tries to move through randomly changing atomic environments.

“With our atomistic calculations, we took the approach of expecting the unexpected and probed not only the usual modes but additional higher modes of slip, typically neglected in the literature to date,” she added. “We also performed thousands of calculations, which exposed just how widely varying this critical dislocation force can be and how favorable alternative higher modes of slip are.”

This study is part of a larger collaborative effort led by Pollock and funded by the US Office of Naval Research, named, which also involves UC Santa Barbara researchers Carlos Levi and Anton van der Ven. This effort is aimed at gaining fundamental insights regarding how best to explore the vast refractory alloy space.

“While compositionally complex alloys have long been of interest to us, progress in exploring the large compositional space has been slow,” said Pollock. “With the MPE project, we brought together a team that used emerging computational, machine learning and experimental tools, which have enabled us to uncover new behaviors and rapidly explore new compositional domains. The very high melting points of the refractory materials of interest have made them notoriously difficult to fabricate and study in the past, but our new approaches, combined with the possibility of 3D printing, completely change the landscape.”

“This work is emblematic of the true power of combining experiments with simulation and theory,” Gianola said. “Many researchers pay lip service to this synergy, but this study could not have gone as far as it did without the constant back and forth between the experimental and simulation groups. The future looks very bright.”

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